Download Binary Lanthanide Oxides by W. Suski, T. Palewski (auth.), H.P.J. Wijn (eds.) PDF

By W. Suski, T. Palewski (auth.), H.P.J. Wijn (eds.)

In subvolume 27C1 magnetic and comparable homes of binary lanthanide oxides were compiled. This subvolume covers information received considering 1980 and will for that reason be considered as complement to quantity III/12c. whereas within the past quantity the vast majority of magnetic information was once got both from magnetometric measurements or from neutron diffraction, for the current info the most emphasis is dedicated to "related" houses with out which, even though, the knowledge of classical magnetic homes is very unlikely. A moment half 27C2 will care for binary oxides of the actinide elements.

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4 Figures and tables Fig. 27. CeO2. EDC in the Ce 5p band region for an evaporated film measured at various photon energies in comparison with the lanthanide 5p photoemission spectra of LaF3 and CeF3 [94MSIT]. On the assumption that the energy separation between the O 2p and O 2s levels in CeO2 is the same as those in the other rare earth oxides, the O 2s level is considered to be located between the features f and g. 1 eV photoexcitation compared with the feature e. On the other hand, the feature e shows weak enhancement around 115 eV, while the feature g does not.

One can observe also that the X3 point is more sensitive than the other X points. The gap between X4' and X3 states decreases from 120 to 50 mRy on reduction of the volume. This is due to the increased hybridization between ∆1 p and f bands and ∆2' f and d bands on increase of pressure. The L2' state, which is at EF at normal pressure, moves up to 10 mRy from EF at high pressure. pressure. The unoccupied part of the DOS consists of mainly three peaks which are mainly derived from Ce d states. 4 Figures and tables [Ref.

The presence of f-character in the bands has no apparent effect on most ground state properties. La n d o l t - B ö r n s t e i n New Series III/27C1 37 Fig. 16. CeO2. 5 eV, i. e. 5 eV (where E1 = εf − Ufc and E2 = 2 E1 + Uff) according to [85KMJP, 86JK]. The spectral intensity is shifted to a lower and narrower energy region. 3 eV) [88JK]. 4 Figures and tables [Ref. p. 121 Fig. 18. CeO2, PrO2 and TbO2. ) [89MB]. The spectra are normalized and the zero of the energy scale is fixed at the first weak absorption structure α.

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