By Arthur Martell, Robert M. Smith
Over the prior fifteen years the fee on Equilibrium facts of the Analytical department of the Inter nationwide Union of natural and utilized Chemistry has been sponsoring a noncritical compilation of steel complicated formation constants and comparable equilibrium constants. This paintings used to be large in scope and led to the book of 2 huge volumes of balance Constants through the Chemical Society (London). the 1st quantity, edited through L. G. Sillen (for inorganic ligands) and through A. E. Martell (for natural ligands), used to be released in 1964 and lined the literature via 1962. the second one quantity, subtitled complement No. 1, edited via L. G. Sillen and E. Hogfeldt (for inorganic ligands) and by way of A. E. Martell and R. M. Smith (for natural ligands), was once released in 1971 and coated the literature as much as 1969. those huge compilations tried to hide all papers within the box relating to steel advanced equi libria (heats, entropies, and unfastened energies). because it was once the coverage of the fee in the course of that interval to prevent judgements about the caliber and reliability of the broadcast paintings, the compilation could often comprise from ten to 20 values for a unmarried equilibrium consistent. in lots of instances the values might fluctuate through one or perhaps orders of importance, therefore not easy readers who desired to use the knowledge with no doing the huge literature examine essential to ensure the proper worth of the consistent in question.
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Extra resources for Critical Stability Constants: Volume 2: Amines
Bibliography: H+ 56SB,58BF,63L,70AB MnZ+ 63L Co 2+ 56SB Ni 2+,Cu Z+ ZnZ+ Cd 2+ 56SB,58BF,70AB 56SB,58BF,63L 56SB,58BF 47 A. L Cd 2+ Log K 100, a Bibliography: (21. 88) L 48 II. 0 L 49 A. 3 (2) II. 76 Bibliography: (4-methoxyphenylenediamine) 71KT A. 2 f lO- 40 °, 0; II. 92)a a Optical isomerism not stated. Bibliography: H+ 65NKS,68NT 2 Ni + 68NT Cu 2+ 65NKS L A.
1 Bibliography: H+ 41GH,65CJ,65R,66HJ,66HP,67HP,67W,6SHA Co 2+,Zn 2+ 66HJ Ni 2+ 56WML,66HJ Cu 2+ 65CJ 25 A. 5 HL 26 II. H Cu Z+ L 57LD,60MC,67R,68Sa,71YM,72BB,7ZTS NiZ+ 57LD,60MC Cu Z+ 57LD,67R,68Sa,71YM,7ZBBL,7ZTS ZnZ+, Cd 2+ 58LC Other reference: 56DR 13 A. 6 L 28 II. 7 Other reference: 73KK 29 A. 35 Bibliography: L 73YN L 30 II. L ML. L ML. 7) Bibliography: H+ 37N,41GH,60MC,66HP,67HP 2 Ni + 60MC Other reference: 56DR A. 09 Bibliography: 73NA L II. 7 33 A. 3 3 2 MLzll--1. H 11. L 2 MLzlM. 1 Bibliography: H+ 65CM,66HP,69PPH Ni 2+_Pb2+ 69PPH Other reference: 55LM (24 ) II.
30 ;'lL/}1. 7 (_ll)a (-3) (4 ) a 10-400, 0 Bibliography: 48BV,53L,59LB Other reference: 2-Furylmethylamine (2-(aminomethyl)furan) Log K 30°, 1. 98 Bibliography: 54GFa 54L L II. 45 Bibliography: H+ L 64NA,66D, 69BH,70VS Cd 2+ 64NA 23 A. 1 (-2) 24 II. 7) 1. 1 Bibliography: H+ 41GH,65CJ,65R,66HJ,66HP,67HP,67W,6SHA Co 2+,Zn 2+ 66HJ Ni 2+ 56WML,66HJ Cu 2+ 65CJ 25 A. 5 HL 26 II. H Cu Z+ L 57LD,60MC,67R,68Sa,71YM,72BB,7ZTS NiZ+ 57LD,60MC Cu Z+ 57LD,67R,68Sa,71YM,7ZBBL,7ZTS ZnZ+, Cd 2+ 58LC Other reference: 56DR 13 A.